Prepare the cake mixture. Crumble the pumpkin cake and cream cheese frosting together in a large bowl until completely combined.
Shape the cake pops. Roll the cake mixture into balls and place them on a parchment-lined baking sheet.
Chill. Chill the cake balls until firm enough to dip and decorate.
Coat the cake pops. Melt the orange and white candy melts according to the package directions. Insert the cake pop sticks and dip each cake pop into the melted candy coating. Allow any excess coating to drip off.
Decorate the scarecrows. Add pieces of shredded wheat cereal for the scarecrow “straw” and mini peanut butter cups for the hats. Allow the candy coating to set completely.
Add the faces. Use an edible food coloring marker to draw the scarecrow faces.